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Methylene Chloride
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Dow, Freeport, TX |
150 |
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Dow, Plaquemine, LA |
150 |
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Vulcan, Geismar, LA |
100 |
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Vulcan, Wichita, KS |
135 |
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Total |
535 |
*Millions of pounds per year.
Methylene chloride (MeC) is coproduced with chloroform in direct reaction of
methyl chloride with chlorine. Capacities are flexible, since more than one
chlorinated hydrocarbon can be produced in the same equipment.
Dow is presently modernizing
its chloromethane plants in Freeport, TX and Plaquemine, LA, but no specific
capacity increase for methylene chloride has been announced.
Profile last published 11/24/97; this
revision, 10/9/00.
DEMAND
1998: 217 million pounds; 1999: 208 million pounds; 2003: 200 million
pounds, projected. Demand equals production plus imports (1998: 37 million
pounds; 1999: 59 million pounds) less exports (1998: 104 million pounds; 1999:
113 million pounds).
GROWTH
Historical (1994 - 1999): -2.3 percent per year; future: 0 percent per year
through 2003.
PRICE
Historical (1994 - 1999): High, $0.43 per pound, tanks, dlvd.; low, $0.40,
same basis. Current: $0.42, same basis. Current market pricing is significantly
lower than list price.
USES
Paint stripping and removal, 30 percent;
adhesives, 20 percent; metal cleaning, 10 percent; aerosols, 10 percent;
pharmaceuticals, 10 percent; chemical processing, 10 percent; flexible
polyurethane foam, 5 percent; miscellaneous, 5 percent.
STRENGTH
Since MeC does not contribute to the formation
of smog in the lower atmosphere, it is not classed as a volatile organic
compound (VOC), or source of smog, by the EPA or under most state and local
regulations. MeC is used as a solvent in cements for clear plastics and is often
blended with other solvents to help dissolve the resin used in contact
adhesives. It is also a major component in adhesives used to construct and
install urethane foam cushions. It is an important component in many aerosol
formulations because of its high solvency. MeC is the primary active ingredient
used in most organic paint removing products, including commercial furniture
strippers, home paint removers, and products used for aircraft maintenance. Its
high solvency, low flammability, and unique ability to penetrate, blister and
lift most types of durable finishes make it the solvent of choice in these
applications. MeC has been the chief substitute for CFC-11 as a flexible
polyurethane foam blowing agent.
WEAKNESS
The Consumer Products Safety Commission (CPSC)
requires that all consumer formulations containing MeC carry warning labels of
potential toxicity. And the National Institute for Occupational Safety and
Health (NIOSH) has classified MeC as a potential occupational carcinogen.
Because of occupational concerns, users of MeC will continue to be under
pressure to limit use, restrict emissions, maximize recycling and eliminate
worker exposure.
OUTLOOK
Since the mid 1980s, increasingly restrictive
government regulations have caused a decline in me MeC consumption. Moreover,
recycling (vapor release capture) and product substitutions have combined to
reduce demand for virgin product. As of April 2000, all compliance deadlines
were to have been satisfied. Those facilities which could not justify investment
in vapor control equipment ceased consuming MeC. Assuming no new restrictions
are imposed, the demand should stabilize around 200 million pounds this year and
continue at that level for the next several years. Although demand in those
industries still served will continue to grow, the negative position of the EPA
toward chlorinated materials in general will encourage further product
substitutions.
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